Cross polarization from (1)H to quadrupolar (6)Li nuclei for dissolution DNP.
نویسندگان
چکیده
Cross polarization from protons to quadrupolar (6)Li nuclei is combined with dynamic nuclear polarization of protons at 1.2 K and 6.7 T using TEMPOL as a polarizing agent followed by rapid dissolution. Compared to direct (6)Li DNP without cross-polarization, a higher nuclear spin polarization P((6)Li) can be obtained in a shorter time. A double resonance (1)H-(6)Li probe was designed that is equipped for Longitudinally Detected Electron Spin Resonance.
منابع مشابه
Hyperpolarization of nitrogen-15 nuclei by cross polarization and dissolution dynamic nuclear polarization.
Dynamic Nuclear Polarization (DNP) is often achieved by the direct transfer of polarization from electrons to nuclei such as 13C, induced by microwave saturation of the wings of narrow EPR lines of radicals like trityl. In the indirect approach on the other hand, DNP is used to transfer the polarization from the electrons of radicals such as nitroxides that have broad EPR lines to nuclear spins...
متن کاملSolid-State Polarization-Transfer Experiments Involving Quadrupolar Nuclei
Historically, cross-polarization experiments [1,2] have been used to transfer spin coherence from abundant spins to a dilute spin system. Protons (*H) have been used almost exclusively as the source of strong nuclear polarization for cross-polarization experiments, although there have been some examples where other abundant nuclei have been used. Coupled with magic-angle spinning (MAS) NMR [3],...
متن کاملDynamic nuclear polarization of quadrupolar nuclei using cross polarization from protons: surface-enhanced aluminium-27 NMR.
The surface of γ-alumina nanoparticles can be characterized by dynamic nuclear polarization (DNP) surface-enhanced NMR of (27)Al. DNP is combined with cross-polarization and MQ-MAS to determine local symmetries of (27)Al sites at the surface.
متن کاملCross-polarization for dissolution dynamic nuclear polarization.
Dynamic nuclear polarization (DNP) in combination with subsequent dissolution of the sample allows the detection of low-γ nuclei in the solution state with a signal gain of up to tens of thousand times compared to experiments starting from Boltzmann conditions. The long polarization build-up times of typically more than one hour are a drawback of this technique. The combination of dissolution D...
متن کاملHigh field dynamic nuclear polarization at 6.7 T: Carbon-13 polarization above 70% within 20 min
In most applications of dissolution-DNP, the polarization of nuclei with low gyromagnetic ratios such as C is enhanced directly by irradiating the ESR transitions of radicals with narrow ESR lines such as Trityl at low temperatures T = 1.2 K in polarizing fields B0 6 5 T. In a field B0 = 6.7 T at T = 1.2 K, DNP with TEMPO leads to a rapid build-up of proton polarization P(H) = 91% with sDNP(H) ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical chemistry chemical physics : PCCP
دوره 16 45 شماره
صفحات -
تاریخ انتشار 2014